1. 研究成果
(1) 提出了释放高价反离子直接成型新工艺,发明了若干种陶瓷浓悬浮体凝固方法,阐明了释放高价反离子在第一极小值固化机制,使陶瓷材料韦伯模数大幅度提高(20-40)。
(2) 通过降低分散剂的分散性能,使陶瓷浓悬浮体Zeta电位降低从而实现原位凝固的方法,成功制备了高可靠性复杂形状的陶瓷部件和材料。
(3) 采用颗粒稳定泡沫技术结合喷雾干燥法,成功制备了工业固体废弃物开孔和闭孔空心微珠。闭孔陶瓷微珠具有轻质、保温隔热功能,成功制备了容重0.1 g/cm3、导热系数0.027 W/mK 的A1级无机防火保温材料。开孔陶瓷空心微珠滤料具有优异的吸附和过滤性能;能够脱色、除异味;可显著降低COD/BOD,在解决大宗工业固体废弃物排放、污水治理、海绵城市建设和土壤修复等领域提出一种以废治废,变废为宝,环境友好、绿色发展循环经济新模式。
(4) 提出胶态成型制备避免应力坯体及方法的学术思想。该学术思想指出:胶态原位凝固成型虽然可以获得密度均匀的坯体,但在液固转变过程中容易产生内应力,内应力将会在干燥、排胶、烧结和机加工的过程中发展、遗传和变异,并且指出克服坯体的内应力将是今后陶瓷胶态成型工艺重要的发展方向。
(5) 发明了高性能陶瓷微珠(0.1-3 mm)普适性的制备方法和装备,建立了一条年产5000吨陶瓷微珠磨介生产线,2005年该项目被世界500强法国圣戈班收购,为地方经济做出突出贡献。将氧化锆陶瓷球珠应用到制笔行业,提高书写寿命5倍以上,被列为中国制笔行业协会十一五重点推广项目,整体提升了我国制笔行业水平。
2. 代表性学术文章
(1) W. Huo, X. Zhang, E. Tervoort, S. Gantenbein, J. Yang, A. R. Studart. Ultrastrong hierarchical porous materials via colloidal assembly and oxidation of metal particles. Advanced Functional Materials. 2020, 2003550.
(2) Jingjing Liu, Bo, Ren, Yuju Lu, Yedong Rong, Chao Wang, Lu Wang, Jinlong Yang, Yong Huang. Mechanically robust ZrO2 foams with 3D reticular architecture prepared from chemical-modified ZrO2 powder. Journal of the American Ceramic Society. 2020, 103(8): 4548−4557.
(3) Jingjing Liu, Bo Ren, Yedong Rong, Yi Zhao, Lu Wang, Yuju Lu, Chao Wang, Guolong Sang, JinlongYang. Highly porous alumina cellular ceramics bonded by in-situ formed mullite prepared by gelation-assisted Al2O3–Si particle-stabilized foams. Ceramics International. 2020, 46(8): 12282-12287.
(4) JingjingLiu, Bo Ren, Kele Liu, Man Yu, Xinglin Li, Zhaoqing Wang, Lu Wang, Jinlong Yang, Yong Huang. Highly porous SiC cellular ceramics for efficient high-temperature PM removal. Ceramics International, 2020, 46(10): 15249-15254.
(5) Jingjing Liu, Bo Ren, Yedong Rong, Yuju Lu, Yi Zhao, Lu Wang, Xiaoqing Xi, Jinlong Yang, Yong Huang. Ultralight and mechanically robust SiC foams with interconnected cellular architecture. Ceramics International, 2020, 46(11): 17962-17968.
(6) J. Liu, H. Yang, B. Ren, Y. Rong, X. Xi, Y. Lu, Y. Zhao, and J. Yang. Highly porous ZrO2 cellular ceramics with 3D network architecture. Ceram. Int., 2020, 46(6): 7149-7154.
(7) K. Gan, Y. Lu, J. Wu, X. Zhang, Y. Wang, B. Ren, W. Huo, Y. Chen, J. Yang. In situ coagulation of yttria-stabilized zirconia ceramic with enhancement of green body via polyvinyl pyrrolidone crosslink. J. Appl. Polym. Sci, 2020, 48889: 1-8.
(8) K.Gan ,Y. Gai. Y. Wang J. Cui Y. Lu X. Zhang. J. Liu. J. Xu. J. Yang. Direct coagulation casting of silicon carbide suspension via polyelectrolyte dispersant crosslink reaction Int. J. Appl. Ceram. Technol. 2020, 17: 274–284.
(9) Y. Lu, K. Gan, J. Liu, B. Ren, X. Zhang, Y. Rong, J. Xu, J. Yang, Gelcasting of alumina via cross-linking of a polyelectrolyte dispersant, Ceramics International, 2020, 46(6): 8308–8313.
(10) Y. Lu, J. Liu, B. Ren, C. Wang, Y. Rong, K. Gan, J. Xu, J. Yang. Room-temperature gelcasting of alumina with tartaric acid and glutaraldehyde. Ceramics International, 2020, 46(8, Part A): 11432–11435.
(11) B. Ren, J. Liu, Y. Rong, L. Wang, Y. Lu, X. Xi, J. Yang. Nanofibrous aerogel bulk assembled by cross-linked SiC/SiOx core−shell nanofibers with multifunctionality and temperature-invariant hyperelasticity. ACS Nano, 2019, 13(10): 11603−11612.
(12) B. Ren, J. Liu, Y. Wang, X. Xi, Y. Lu, R. Yedong, L. Wang, Y. Chen, J. Yang. Highly porous and hierarchical MgAl2O4 ceramics with improved pore connectivity prepared from gelled particle-stabilized foams. Ceram. Int., 2019, 45(14): 17489-17494.
(13) B. Ren, J. Liu, Y. Wang, Y. Chen, K. Gan, Y. Rong, J. Yang. Hierarchical cellular scaffolds fabricated via direct foam writing using gelled colloidal particle-stabilized foams as the ink. J. Am. Ceram. Soc.,2019, 102(11): 6498-6506.
(14) B. Ren, J. Liu, W. Huo, K. Gan, S. Yan, Y. Chen, Y. Lu, J. Yang, Y. Huang. Three-dimensional (3D) flexible nanofibrous network knitting on hierarchical porous architecture. J. Am. Ceram. Soc., 2019, 102(5): 2977-2986.
(15) B. Ren, Y. Wang, J. Liu, X. Zhang, Y. Chen, Y. Rong and J. Yang. Preparation of Al2O3-Si3N4 porous ceramics with a cactus-like architecture for potential filters applications. Ceram. Int., 2019, 45(5): 6581-6584.
(16) B. Ren, J. Liu, W. Huo, K. Gan, Y. Lu, Y. Chen, L. Wang, J. Yang and Y. Huang. Facile fabrication of nanofibrous network reinforced hierarchical structured porous Si3N4-based ceramics based on Si-Si3N4 binary particle-stabilized foams. Ceram. Int., 2019, 45(2): 1984-1990.
(17) J. Liu, B. Ren, S. Zhang, Y. Lu, Y. Chen, L. Wang, J. Yang, and Y. Huang. Hierarchical ceramic foams with 3D interconnected network architecture for superior high-temperature particulate matter capture. ACS. Appl. Mater. Interfaces., 2019, 11: 40585-40591.
(18) J. Liu, B. Ren, Y. Wang, Y. Lu, L. Wang, Y. Chen, J. Yang, and Y. Huang. Hierarchical porous ceramics with 3D reticular architecture and efficient flow-through filtration towards high-temperature particulate matter capture. Chem. Eng. J., 2019, 362: 504-512.
(19) J. Liu, B. Ren, Y. Chen, Y. Lu, S. Zhang, Y. Rong, and J. Yang. Novel design of alumina foams with three-dimensional reticular architecture for effective high-temperature particulate matter capture. J. Am. Ceram. Soc., 2019, 102(9): 5576-5586.
(20) J. Liu, B. Ren, Y. Lu, X. Xi, Y. Li, K. Liu, J. Yang, and Y. Huang. Novel design of elongated mullite reinforced highly porous alumina ceramics using carbonized rice husk as pore-forming agent. Ceram. Int., 2019, 45: 13964-13970.
(21) Lu Y, Gan K, Xu J, et al. Dispersion and gelation properties of alumina systems with Isobam assisted by dicarboxylic acids. Ceramics International, 2019, 45(9): 11939–11945.
(22) Y. Chen, W. Huo, X. Zhang, Y. Lu, S. Yan, J. Liu, K. Gan, and J. Yang. Ultrahigh-Strength Alumina Ceramic Foams via Gelation of Foamed Boehmite Sol. J. Am. Ceram. Soc., 2019, 102(9): 5503-5513.
(23) Shu Yan, Fanyong Zhang, Jingjing Liu, Bo Ren, Peigang He, Dechang Jia, Jinlong Yang. Green synthesis of high porosity waste gangue microsphere/geopolymer composite foams via hydrogen peroxide modification. Journal of Cleaner Production, 2019, 227: 483-494.
(24) Shu Yan, Qinggang Wang, Fanyong Zhang, Xiaoyan Zhang, Yuju Lu, Ke Gan, Wenlong Huo, Shuhao Zhang, Jingjing Liu, Jinlong Yang. Low-cost, green synthesis and adsorption properties for dyes of novel porous gangue/palygorskite composite microspheres. International Journal of Applied Ceramic Technology, 2019, 16(4): 1510-152.
(25) Shu Yan, Qinggang Wang, Jingjing Liu, Wenlong Huo, Jinlong Yang, Yong Huang. Synthesis, Characterization and Adsorption Properties of Low-cost Porous Calcined Dolomite Microspheres for Removal of Dyes. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2019, 34(3): 507-515.
(26) W. Huo, X. Zhang, K. Gan, Y. Chen, Y. Lu, J. Xu, J. Yang. Effect of zeta potential on properties of foamed suspension. Journal of the European Ceramic Society, 2019, 39(2-3):574-538.
(27) W. Huo, X. Zhang, Y. Chen, Z. Hu, D. Wang, J. Yang, Ultralight and high-strength bulk alumina/zirconia composite ceramic foams through direct foaming method, Ceramic International, 2019, 45(1):1464-1467.
(28) W. Huo, X. Zhang, K. Gan, H. Li, S. Yan, Y. Chen, J. Yang. Ceramic particle-stabilized foams/emulsions with UV light response and further synthesis of ceramic capsules, Chemical Engineering Journal. 2019, 360:1458-1467.
(29) W. Huo, X. Zhang, Z. Hu, Y. Chen, Y. Wang, J. Yang. Silica foams with ultra-large specific surface area structured by hollow mesoporous silica spheres. Journal of the American Ceramic Society. 2019, 102(3): 955-961.
(30) W. Huo, X. Zhang, S. Hou, Y. Chen, Y. Wang, J. Yang. Aerogel-like Ceramic Foams with Super-high Porosity and Nanoscale Cell Wall from Sol Nanoparticles Stabilized Foams. Journal of the American Ceramic Society. 2019, 102(6): 3753-3762.
(31) W. Huo, X. Zhang, J. Xu, Z. Hu, S. Yan, K. Gan, J. Yang. In-situ synthesis of three-dimensional nanofiber-knitted ceramic foams via reactive sintering silicon foams, Journal of the American Ceramic Society. 2019, 102(5): 2245-2250.
(32) W. Huo, X. Zhang, B. Ren, J. Liu, D. Wang, J. Yang. Preparation of ultra-stable foams stabilized by large-size platelet particles via direct foaming method. Journal of Ceramic Science and Technology, 2019, 10(1): 39-43.
(33) X. Zhang, W. Huo, Y. Chen, Z. Hu, Y. Wang, K. Gan, J. Yang. Novel micro-spherical Si3N4 nanowire sponges from carbon-doped silica sol foams via reverse templating method, J. Am. Ceram. Soc. 2019, 102(3): 962-969.
(34) X. Zhang, W. Huo, K. Gan, Y. Wang, Z. Hu, J. Yang. Si3N4 hollow microsphere toughened porous ceramics from direct coagulation method via dispersant reaction. Adv. Eng. Mater.. 2019, 21(3): 1800858.
(35) X. Zhang, W. Huo, Y. Lu, K. Gan, S. Yan, J. Liu, J. Yang. Porous Si3N4-based ceramics with uniform pore structure originated from single-shell hollow microspheres. J. Mater. Sci., 2019, 54: 4484-4494.
3. 专著
黄 勇,杨金龙 著,《Novel colloidal forming of ceramics》(第一版),Springer出版社和永利yl23411官网出版社联合出版(全英文专著),2010。
杨金龙,黄 勇 著,《Novel colloidal forming of ceramics》(第二版),Springer出版社和永利yl23411官网出版社联合出版(全英文专著),2020。
杨金龙,许杰,干科,《陶瓷浓悬浮体新型固化技术及其原理》,永利yl23411官网出版社,2020
杨金龙,席小庆,黄 勇 著,《陶瓷微珠》,永利yl23411官网出版社;2017。
黄 勇,杨金龙,汪长安 编著,《无机非金属材料题解指南》,永利yl23411官网出版社,2017。
4. 代表性授权专利
(1) 杨金龙, 干科, 杨洁, 等. 一种碳纳米管/陶瓷基复合材料的制备方法: 中国发明专利, 专利号: 201910116646.9. 授权日期: 2020-12-08
(2) 杨金龙, 张在娟, 唐欣悦, 等. 一种利用水性聚氨酯增强超轻泡沫陶瓷坯体强度的方法: 中国发明专利, 专利号: 201711116601.9. 授权日期: 2020-07-07
(3) 杨金龙, 霍文龙, 陈雨谷, 等. 一种以废玻璃为原料制备微米级气孔结构可调的泡沫玻璃的方法: 中国发明专利, 专利号: 201710334878.2. 授权日期: 2020-08-21
(4) 杨金龙, 霍文龙, 张笑妍, 等. 一种增强超轻泡沫陶瓷坯体强度的方法: 中国发明专利, 专利号: 201710352108.0. 授权日期: 2020-01-21
(5) 杨金龙, 霍文龙, 张笑妍, 等. 一种利用中空微球制备具有连通孔壁泡沫陶瓷的方法: 中国发明专利, 专利号: 201810883586.9. 授权日期: 2020-08-25
(6) 杨金龙, 霍文龙, 张笑妍, 等. 一种制备泡沫氧化铝和泡沫铝/氧化铝复合材料的方法: 中国发明专利, 专利号: 201810384689.0. 授权日期: 2020-12-15
(7) 杨金龙, 霍文龙, 张笑妍, 等. 一种反向模板法制备纳米线编织微球的陶瓷海绵材料方法: 中国发明专利, 专利号: 201810883488.5. 授权日期: 2020-08-14
(8) 杨金龙, 闫姝, 王璐, 等. 煤矸石空心微珠/铝硅酸盐聚合物复合吸附剂及其制备方法: 中国发明专利, 专利号: 201810229119.4. 授权日期: 2020-08-21
(9) 杨金龙, 张在娟, 唐欣悦, 等. 一种基于敲击声波法的天线罩无损检测装置与方法: 中国发明专利, 专利号: 201810238899.9. 授权日期: 2020-10-27
(10) 杨金龙,霍文龙, 林鸿福, 等. 具有保温性能的日用多孔复合陶瓷及其制备方法: 中国发明专利, 专利号: 201610850059.9. 授权日期:2019-10-11
(11) 杨金龙, 张笑妍, 李娜,等,一种多孔石英陶瓷的制备方法.中国发明专利,专利号:201610056581.X,授权日期:2018-12-18
(12) 杨金龙,李志君,苏振国,等,一种以空心微珠为原料的陶粒及其制备方法.中国发明专利,专利号:201610219693.2,授权日期:2018-06-05
(13) 杨金龙, 马宁, 张月, 等. 一种一步法制备的有序介孔有机氧化硅空心球及其制备方法. 中国发明专利, 专利号: 201510427967.2, 授权日期: 2017-03-01
(14) 杨金龙, 马宁, 张月, 等. 一种易溶解的氧化硅球、其制备方法及应用. 中国发明专利, 专利号: 201510428142.2, 授权日期: 2017-04-12
(15) 杨金龙, 许杰, 杨名昊, 等. 一种聚磷酸盐螯合物控释高价反离子固化陶瓷浆料的方法. 中国发明专利, 专利号: 201510170233.0, 授权日期: 2017-04-12
(16) 杨金龙, 渠亚男, 席小庆, 等. 一种测试高温发泡过程的方法. 中国发明专利,专利号: 201510065287.0, 授权日期: 2017-08-11
(17) 杨金龙, 陈金德, 席小庆, 等. 一种无机微球快速烧结的方法与装置. 中国发明专利.专利号: 201310528555.9, 授权日期: 2016-03-09
(18) 杨金龙, 齐飞, 许杰, 等. 一种超轻质闭孔陶瓷的制备方法. 中国发明专利.专利号: 201410253455.4, 授权日期: 2016-06-15
(19) 杨金龙, 苏振国, 席小庆, 等. 一种利用煤矸石空心微珠自发泡制备无机泡沫材料的方法, 中国发明专利, 专利号: 201310132817.X, 授权日期: 2016-05-11
(20) 杨金龙, 苏振国, 席小庆, 等. 一种利用废玻璃制备微孔泡沫玻璃的方法. 中国发明专利, 专利号: 201310529973.X, 授权日期: 2015-12-09
(21) 杨金龙, 吴甲民, 张笑妍, 等. 一种采用陶瓷空心球制备多孔陶瓷的方法. 中国发明专利, 专利号: 201310430728.3, 授权日期: 2015-10-28
(22) 杨金龙, 许杰, 渠亚男, 等. 通过缓慢调节pH值控制高价反离子固化陶瓷浆料的方法. 中国发明专利, 专利号: 201410009146.2, 授权日期: 2015-4-15
(23) 杨金龙, 许杰, 渠亚男, 等. 一种非氧化物陶瓷的直接凝固注模成型方法. 中国发明专利, 专利号: 201410130619.4, 授权日期: 2015-4-15
(24) 杨金龙, 申殿军, 席小庆, 等. 运动员力竭运动后快速恢复系统. 中国发明专利, 专利号: 201210525897.0, 授权日期: 2015-07-08
(25) 杨金龙, 许杰, 温宁, 等. 一种温度控制高价反离子缓释固化陶瓷浆料的方法. 中国发明专利, 专利号: 201110291426.3, 授权日期: 2014-01-01
(26) 杨金龙, 苏振国, 席小庆, 等. 一种具有二级闭孔结构的无机保温材料及其制备方法. 中国发明专利, 专利号: 201210282748.6, 授权日期: 2014-06-25
(27) 杨金龙, 温宁, 许杰, 等. 一种通过缓释高价反离子实现陶瓷浆料直接凝固成型的方法. 中国发明专利, 专利号: 201110140027.7, 授权日期: 2014-09-17
(28) 杨金龙, 苏振国, 席小庆, 等. 一种具有三级孔结构的无机保温材料及其制备方法. 中国发明专利, 专利号: 201210592778.7, 授权日期: 2014-09-24
(29) 杨金龙, 马宁, 龙梦龙, 等. 一种微米级蜂窝陶瓷及其孔径和孔壁尺寸的调控方法. 中国发明专利, 专利号: 201310164617.2, 授权日期: 2014-09-24